Theoretical infrared spectra of some model polycyclic aromatic hydrocarbons: effect of ionization     

De Frees DJ  Miller MD  Talbi D  Pauzat F  Ellinger Y 《The Astrophysical journal》1993,408(2):530-538

In order to test the hypothesis of ionized polycyclic aromatic hydrocarbons (PAHs) as possible carriers of the UIR bands, we realized a computational exploration on selected PAHs of small dimension in order to identify which changes ionization would induce on their IR spectra. In this study we performed ab initio calculations of the spectra of neutral and positively ionized naphthalene, anthracene, and pyrene. The results are significantly important. The frequencies in the cations are slightly shifted with respect to the neutral species, but no general conclusion can be reached from the three molecules considered. By contrast, the relative intensities of most vibrations are strongly affected by ionization, leading to a much better agreement between the calculated CH/CC vibration intensity ratios and those deduced from observations.  相似文献   

Čerenkov radiation within the Earth's upper atmosphere     

S. S. De  B. Ghosh  B. K. Sarkar  M. De  S. K. Adhikari 《Earth, Moon, and Planets》1993,61(2):169-173

A brief review of erenkov radiation within the upper atmospheric plasma has been presented. Different attempts in this context are systematically discussed. The results of analysis about the nature and characteristics of VLF hisses in terms of incoherent erenkov radiation are given in a concise manner. The occurrence of resonance cone has also been reported.  相似文献   

Determination of a New Failure Criterion for Rock Mass and Concrete     

Ucar  Roberto 《Geotechnical and Geological Engineering》2021,39(5):3795-3813

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Molecular indicators for palaeoenvironmental change in a Messinian evaporitic sequence (Vena del Gesso, Italy). II: High-resolution variations in abundances and 13C contents of free and sulphur-bound carbon skeletons in a single marl bed     

Kenig F  Damsté JS  Frewin NL  Hayes JM  De Leeuw JW 《Organic Geochemistry》1995,23(6):485-526

The extractable organic matter of 10 immature samples from a marl bed of one evaporitic cycle of the Vena del Gesso sediments (Gessoso-solfifera Fm., Messinian, Italy) was analyzed quantitatively for free hydrocarbons and organic sulphur compounds. Nickel boride was used as a desulphurizing agent to recover sulphur-bound lipids from the polar and asphaltene fractions. Carbon isotopic compositions (delta vs PDB) of free hydrocarbons and of S-bound hydrocarbons were also measured. Relationships between these carbon skeletons, precursor biolipids, and the organisms producing them could then be examined. Concentrations of S-bound lipids and free hydrocarbons and their delta values were plotted vs depth in the marl bed and the profiles were interpreted in terms of variations in source organisms, 13 C contents of the carbon source, and environmentally induced changes in isotopic fractionation. The overall range of delta values measured was 24.7%, from -11.6% for a component derived from green sulphur bacteria (Chlorobiaceae) to -36.3% for a lipid derived from purple sulphur bacteria (Chromatiaceae). Deconvolution of mixtures of components deriving from multiple sources (green and purple sulphur bacteria, coccolithophorids, microalgae and higher plants) was sometimes possible because both quantitative and isotopic data were available and because either the free or S-bound pool sometimes appeared to contain material from a single source. Several free n-alkanes and S-bound lipids appeared to be specific products of upper-water-column primary producers (i.e. algae and cyanobacteria). Others derived from anaerobic photoautotrophs and from heterotrophic protozoa (ciliates), which apparently fed partly on Chlorobiaceae. Four groups of n-alkanes produced by algae or cyanobacteria were also recognized based on systematic variations of abundance and isotopic composition with depth. For hydrocarbons probably derived from microalgae, isotopic variations are well correlated with those of total organic carbon. A resistant aliphatic biomacromolecule produced by microalgae is, therefore, probably an important component of the kerogen. These variations reflect changes in the depositional environment and early diagenetic transformations. Changes in the concentrations of S-bound lipids induced by variations in conditions favourable for sulphurization were discriminated from those related to variations in primary producer assemblages. The water column of the lagoonal basin was stratified and photic zone anoxia occurred during the early and middle stages of marl deposition. During the last stage of the marl deposition the stratification collapsed due to a significant shallowing of the water column. Contributions from anaerobic photoautotrophs were apparently associated with variations in depth of the chemocline.  相似文献   

Late stages of the evolution of close binaries     

C. De Loore  W. Sutantyo 《Astrophysics and Space Science》1984,99(1-2):335-354

Close binaries can evolve through various ways of interaction into compact objects (white dwarfs, neutron stars, black holes). Massive binary systems (mass of the primaryM ₁ larger than 14 to 15M ₀) are expected to leave, after the first stage of mass transfer a compact component orbiting a massive star. These systems evolve during subsequent stages into massive X-ray binaries. Systems with initial large periode evolve into Be X-ray binaries.Low mass X-ray sources are probably descendants of lower mass stars, and various channels for their production are indicated. The evolution of massive close binaries is examined in detail and different X-ray stages are discussed. It is argued that a first X-ray stage is followed by a reverse extensive mass transfer, leading to systems like SS 433, Cir X1. During further evolution these systems would become Wolf-Rayet runaways. Due to spiral in these system would then further evolve into ultra short X-ray binaries like Cyg X-3.Finally the explosion of the secondary will in most cases disrupt the system. In an exceptional case the system remains bound, leading to binary pulsars like PSR 1913+16. In such systems the orbit will shrink due to gravitational radiation and finally the two neutron stars will coalesce. It is argued that the millisecond pulsar PSR 1937+214 could be formed in this way.A complete scheme starting from two massive ZAMS stars, ending with a millisecond pulsar is presented.Paper presented at the Lembang-Bamberg IAU Colloquium No. 80 on Double Stars: Physical Properties and Generic Relations, held at Bandung, Indonesia 3–7 June, 1983.  相似文献   

Close binary systems before and after mass transfer: A comparison of observations and theory     

J. P. De Grève  D. Vanbeveren 《Astrophysics and Space Science》1980,68(2):433-457

From a search through the literature 174 close binaries with known absolute dimensions have been sampled. Distinction is made between systems before and after mass exchange. Mass, period and mass ratio distributions and relations of the group of unevolved binaries (i.e., prior to mass exchange) are transformed into corresponding distributions and relations of evolved binaries. The transformations are based upon theM _1f=g(M _1f) relation derived from an extended set of published theoretical computations of the evolution of close binaries. From this relation the following characteristics of the system after mass exchange are computed:M _1f,M _2f (andq _f),P _f. Five different modes of mass transfer were applied for the computation of the values ofP _f andM _2f. The variation of the period was calculated using the formalism given by Vanbeverenet al. (1979). The results are compared to the observations of binary systems after mass exchange, and are discussed together with an analysis of the effect of several selection effects present in the distributions. The main conclusion is that, during mass exchange in close binaries, more than 50% of the mass is lost to the system in the process of transfer, removing a large amount of angular momentum.This research is supported by the National Foundation of Collective Fundamental Research of Belgium (F.K.F.O.) under No. 2.9009.79.  相似文献   

Protoplanetary core formation by rain-out of minerals     

W. L. Slattery  W. M. De Campli  A. G. W. Cameron 《Earth, Moon, and Planets》1980,23(4):381-390

Models of giant gaseous protoplanets calculated by DeCampli and Cameron (1979) indicate that iron and probably other minerals in the interior of a planet would be in the liquid state during part of the protoplanet evolution. Liquid drops in a protoplanet would grow by coalescence much as cloud drops in the Earth's atmosphere grow to rain drops. We have modeled this process by using the stochastic collection equation (Slattery, 1978) for various initial conditions. In all of the cases considered, the growth time (to centimeter-sized droplets) is much shorter than the time, as estimated by detailed evolutionary calculations, that the drops are in the liquid state. Brownian collection is effective in quickly coalescing tiny liquid droplets to an average radius of about 0.005 cm with very few drops remaining with radii less than 0.001 cm. For radii larger than 0.005 cm gravitational collection is dominant. Since the particles are rapidly swept from interstellar grain sizes to much larger sizes, the opacity in the cloud layer is expected to drop sharply following melting of the grains.  相似文献   

Bifurcation points in close binary evolution: Medium-mass binaries     

J. P. De Grève 《Astrophysics and Space Science》1982,84(2):447-456

The remaining core hydrogen burning lifetime after case B of mass transfer of the secondary (mass gaining) component in a medium mass close binary star is estimated, for mediummass binaries with primaries in the mass range 5M to 9M . From the comparison of this quantity with the helium burning time-scale of the remnant primary a critical mass ratioq _c is derived such that for larger values ofq, mass transfer from the secondary towards the primary starts before the latter has evolved into a white dwarf. Consequences for the advanced stages of medium mass binaries are discussed.  相似文献   

Comparison of two methods for seismic hazard assessment in a low-seismicity area     

Th. De Crook  J. J. Egozcue 《Natural Hazards》1992,6(1):39-49

The EGO method, developed by Egozcue et al. and the SRAMSC method, originally developed by Cornell and later programmed by McGuire, to assess the seismic hazard, are compared for the low seismicity area Belgium, The Netherlands, and NW Germany. Using the same input data, the results of the EGO method without the majority criterion and the SRAMSC method with upper bound XII agree very well. The influence of the zoning is investigated for the EGO method. It is not necessary to define the zones for the EGO method so strictly as for the SRAMSC method, but too wide zones can give bad results.  相似文献   

Analysis of hydrologic relations between Eğirdir-Beyşehir-Suğla lakes system and adjacent basins by means of remote sensing techniques (southern Turkey)     

Mustafa Değirmenci  Gültekin Günay 《Environmental Geology》1992,19(1):41-45

The study area is situated within the complex structure and karst system of the western Taurids. Basinwide interpretation of the structural features, each of which has great importance, will enlighten many complicated hydrogeologic problems encountered in the area. Thus, considering the previous views on the structural geology of the area, an interpretation of the structural and tectonic features of the study area by means of satellite images was undertaken, and based on the data gained, new approaches were suggested to solve the hydrogeological problems. In particular, determination of the recharge-discharge mechanisms of the Olukköprü and Dumanli karst springs, which are the most important karst groundwater discharge points in the region, has been attempted. Within the framework of this study, a tectonic-lineament map of a large area covering Eirdir, Beyehir, and Sula lakes at the north and the basins to the south of these lakes was prepared.  相似文献